Thermodynamic modeling of ternary liquid-liquid systems with forming immiscibility islands
نویسندگان
چکیده
منابع مشابه
Liquid-Liquid Equilibrium for the Ternary Systems of Solvent+ m/o/p-Cresol+Water: Thermodynamic Modeling
In this study, NRTL and UNIQUAC thermodynamic models were used to predict the composition of ternary mixtures of solvents+ m/o/p-cresol+ water in organic and aqueous phases. Various solvents are used for the separation of cresols from water. In this study, methyl propyl ketone, methyl isopropyl ketone, methyl butyl ketone, and methyl isobutyl ketone solvents were investigated. Intermolecular in...
متن کاملLiquid-liquid immiscibility in lipid monolayers.
Some binary lipid mixtures form coexisting liquid phases when spread at the air/water interface. This work describes the pressure-composition phase diagrams of binary mixtures of four unsaturated phosphatidylcholines with dihydrocholesterol. These four binary mixtures have critical compositions of approximately fifty mole percent, and average critical exponents of 0.25 +/- 0.07. The data can al...
متن کاملLiquid-Liquid Immiscibility in Pure Fluids: Polyamorphism in Simulations of a Network-Forming Fluid.
We report Monte Carlo simulations that show both vapor-liquid and closed-loop liquid-liquid equilibrium in a pure substance, for a model fluid that forms orientation-dependent intermolecular bonds. This is the first time that direct evidence of liquid-liquid immiscibility in a pure fluid has been found using exact methods. Because the model is formulated in terms of a tetrahedrally coordinated ...
متن کاملEffect of Magnetic Field on the Liquid-liquid Equilibria of (Water + Acetic Acid + Organic Solvent) Ternary Systems
The effect of magnetic field on the liquid-liquid equilibrium of two ternary systems (water + acetic acid + butyl acetate and water + acetic acid + dimethyl succinate) at 298.15 K under atmospheric pressure was investigated. The results obtained show that the strength of the magnetic field (0.02 T) affects the solubility of acetic acid in the used organic solvents. Distribution coefficients and...
متن کاملModeling of liquid–liquid equilibria of aqueous alcohol + salt systems using amodified NRTL
The modified NRTL (m-NRTL) model is used to represent the excess Gibbs free energy of aqueous (alcohol + electrolyte) solutions. In this work, the m-NRTL model previously developed for representation of vapor-liquid equilibria for (polymer + salt + water) systems has been extended to represent liquid-liquid equilibria of (alcohol + salt + water) systems. The proposed extension is a modified of ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Brazilian Archives of Biology and Technology
سال: 2013
ISSN: 1516-8913
DOI: 10.1590/s1516-89132013000600020